TOP 22 IMPORTANT QUATIONs WITH ANSWER OF CLASS 11 - THERMODYNAMICS (MCQs)
TOP 22 IMPORTANT QUATIONs WITH ANSWER OF CLASS 11 - THERMODYNAMICS (MCQs)
Class 11 chemistry MCQs with answers are provided here for chapter 6 Thermodynamics. These MCQs are based on CBSE board curriculum and correspond to the most recent Class 11 chemistry syllabus. By practicing these Class 11 Multiple choice questions, students will be able to quickly review all of the ideas covered in the chapter and prepare for the Class 11 Annual examinations as well as other entrance exams such as NEET and JEE.
1. A well stoppered thermos flask contains some ice cubes. This is an example of
(a) Closed system
(b) Open system
(c) Isolated system
(d) Non thermodynamics system
Ans: (c)
Solution: It is an isolated system
2. For the reaction C(s) + O2(g) → CO2(g)
(a) △H >△U
(b) △H < △U
(c) △H = △U
(d) None of these
Ans: (c)
Solution: Here △ng RT = 0 , because reactant and product contain same number of gaseous molecules. So that △H = △U + △ng RT ⇒ △H = △U
3. For an ideal gas, CV and CP are related as :
(a) CV – CP = R
(b) CV + CP = R
(c) CP – Cv = RT
(d) CP – Cv = R
Ans: (d) CP – Cv = R
Solution: For an ideal gas, CV and CP are related as CP – Cv = R
4. The least random state of the water system is:
(a) ice
(b) liquid water
(c) steam
(d) randomness is same
Ans: (a)
Solution: The least random state of the water system is ice.
5. Considering entropy(S) thermodynamic parameters the criteria for the spontaneity of any process is:
(a) △S system + △S surroundings > 0
(b) △S system – △S surroundings < 0
(c) △S system > 0
(d) △S surroundings > 0
Ans: (a)
Solution: The criteria for the spontaneity of any process is
△S system + △S surroundings > 0
6. The enthalpy change in a reaction does not depend upon
(a) the state of reactions and products
(b) the nature of the reactants and products
(c) different intermediate steps in the reaction
(d) initial and final enthalpy of the reaction
Ans: (c)
Solution: The enthalpy change is a state function so it doesn’t depend on different intermediate steps in the reaction.
7. The correct relationship between free energy change in a reaction and the corresponding equilibrium constant KC is
(a) -△G = RT lnKC
(b) △G0 = RT lnKC
(c) -△G0 = RT lnKC
(d) △G = RT lnKC
Ans: (c)
Solution : The relationship between free energy change in a reaction and the corresponding equilibrium constant KC is △G0 = – RT lnKC or -△G0 = RT lnKC
8. What is the entropy change (in JK-1 mol-1) when 1 mole of ice is converted into water at 0℃? (The enthalpy change for the conversion of ice to liquid water is 6.0 kJ mol-1 at 0℃)
(a) 20.13
(b) 2.013
(c) 2.198
(d) 21.98
Ans: (d)
Solution: The entropy change; ds = dqrev /T ⇒ ds = 6000J mol-1 / 273K
⇒ ds = 21.978JK-1 mol-1
9. If liquids A and B form an ideal solution
(a) the entropy of mixing is zero
(b) the free energy of mixing is zero
(c) the free energy as well as the entropy of mixing are zero
(d) the enthalpy of mixing is zero
Ans: (d)
Solution: If liquids A and B form an ideal solution the enthalpy of mixing is zero
10. When water is added to quick lime the reaction is
(a) Explosive
(b) endothermic
(c) exothermic
(d) photochemical
Ans: (c)
Solution: When water is added to quick lime the reaction is exothermic
CaO + H2O → Ca(OH)2 △H = -ve
11. What is thermodynamics?
a) study of the relationship between heat and other forms of energy
b) study of the conversion of chemical energy to other forms of energy
c) study of the relationship between mechanical energy to other forms of energy
d) study of the conversion of mechanical energy to other forms of energy
Answer: a
12. Which of the following is an application of thermodynamics?
a) Refrigerators
b) Gas compressors
c) Power plants
d) All of the mentioned
Answer: c
13. Which of the following is a type of thermodynamic system?
a) Open system
b) Closed system
c) Thermally isolated system
d) All of the mentioned
Answer: d
14. Which of the following occurs without a change in the internal energy?
a) Isochoric process
b) Isenthalpic process
c) Steady-state process
d) Isenthalpic process
Answer: c
15. Which of the following thermodynamic law gives the concept of enthalpy?
a) First law of thermodynamics
b) Second law of thermodynamics
c) Third law of thermodynamics
d) Fourth law of thermodynamics
Answer: c
16. What is the value of the absolute thermodynamic temperature scale?
a) 3K
b) 0K
c) 1K
d) 4K
Answer: b
17. If a piston/cylinder with a cross-sectional size of 0.01 m2 is resting on the stops, what should the water pressure be to lift the piston with an outside pressure of 100 kPa?
a) 218kPa
b) 168kPa
c) 198kPa
d) 318kPa
Answer: c
18. At 100°C, a sealed rigid vessel with a volume of 1 m3 and 2 kg of water has a volume of 1 m3. The vessel has now been warmed up. What pressure should a safety pressure valve be adjusted to achieve a maximum temperature of 200°C if one is installed?
a) 431.3 kPa
b) 231.3 kPa
c) 831.3 kPa
d) 131.3 kPa
Answer: a
19. When the diver is 8 meters below the surface, the pressure gauge on his air tank reads 60 kPa. The gauge pressure will be 0 at what depth?
a) 44.118 m
b) 24.118 m
c) 34.118 m
d) None of the mentioned
Answer: b
19. Which of the following is the standard fixed point of thermometry?
a) The steam point
b) The triple point of water
c) The ice point
d) All of the mentioned
Answer: b
20. Which of the following is the standard fixed point of thermometry?
a) The steam point
b) The triple point of water
c) The ice point
d) All of the mentioned
Answer: b
21. Which of the following gives the Mechanical efficiency of the engine?
a) IP/BP
b) 1/(BP*IP)
c) (BP*IP)
d) BP/IP
Answer: d
22. Rate of energy increase within the control volume is given by
a) rate of energy inflow * rate of energy outflow
b) rate of energy inflow – rate of energy outflow
c) rate of energy inflow / rate of energy outflow
d) rate of energy inflow + rate of energy outflow
Answer: b
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